全文获取类型
收费全文 | 169篇 |
免费 | 17篇 |
国内免费 | 50篇 |
专业分类
安全科学 | 23篇 |
废物处理 | 8篇 |
环保管理 | 10篇 |
综合类 | 102篇 |
基础理论 | 32篇 |
污染及防治 | 26篇 |
评价与监测 | 21篇 |
社会与环境 | 5篇 |
灾害及防治 | 9篇 |
出版年
2023年 | 6篇 |
2022年 | 18篇 |
2021年 | 20篇 |
2020年 | 9篇 |
2019年 | 9篇 |
2018年 | 5篇 |
2017年 | 10篇 |
2016年 | 5篇 |
2015年 | 7篇 |
2014年 | 15篇 |
2013年 | 10篇 |
2012年 | 13篇 |
2011年 | 14篇 |
2010年 | 13篇 |
2009年 | 10篇 |
2008年 | 7篇 |
2007年 | 6篇 |
2006年 | 11篇 |
2005年 | 9篇 |
2004年 | 6篇 |
2003年 | 3篇 |
2002年 | 7篇 |
2001年 | 3篇 |
2000年 | 4篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1995年 | 2篇 |
1994年 | 3篇 |
1993年 | 1篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1988年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有236条查询结果,搜索用时 265 毫秒
71.
改进的还原偶氮光度法同时快速测定水中硝基苯和苯胺 总被引:1,自引:1,他引:0
对测定方法进行了改进,建立了用还原-偶氮分光光度法同时快速测定水中硝基苯和苯胺的分析方法。根据实验原理,对样品前处理装置进行了改进,实验步骤得到了简化,避免了样品溶液过滤转移过程造成样品损失,使样品前处理实验效率提高了90%以上;改进后的测定方法不仅可快速测定样品中硝基苯,还可同时测定样品中苯胺;达到了用一种分析方法同时测定样品中两种污染物的目的。方法精密度测定结果,相对标准偏差(n=6,RSD)为1.9%~3.2%;对硝基苯、苯胺混合标准样品以及实际废水样品进行了测定,并与原测定方法及苯胺国标测定方法进行了比对实验;测定结果具有一致性。加标实验回收率为96%~101%,表明方法准确可靠,可用于水和废水中硝基苯或硝基苯和苯胺的同时测定。 相似文献
72.
This review aimed to systematically summarize the epidemiological literature on the cardiorespiratory effects of PM2.5 published during the 13th Five-Year Plan period (2016–2020) in China. Original articles published between January 1, 2016 and June 30, 2021 were searched in PubMed, Web of Science, the China National Knowledge Internet Database and Wanfang Database. Random- or fixed-effects models were used to pool effect estimates where appropriate. Of 8558 records identified, 145 met the full eligibility criteria. A 10 µg/m³ increase in short-term PM2.5 exposure was significantly associated with increases of 0.70%, 0.86%, 0.38% and 0.96% in cardiovascular mortality, respiratory mortality, cardiovascular morbidity, and respiratory morbidity, respectively. The specific diseases with significant associations included stroke, ischemic heart disease, heart failure, arrhythmia, chronic obstructive pulmonary disease, pneumonia and allergic rhinitis. The pooled estimates per 10 µg/m³ increase in long-term PM2.5 exposure were 15.1%, 11.9% and 21.0% increases in cardiovascular, stroke and lung cancer mortality, and 17.4%, 11.0% and 4.88% increases in cardiovascular, hypertension and lung cancer incidence respectively. Adverse changes in blood pressure, heart rate variability, systemic inflammation, blood lipids, lung function and airway inflammation were observed for either short-term or long-term PM2.5 exposure, or both. Collectively, we summarized representative exposure-response relationships between short- and long-term PM2.5 exposure and a wide range of cardiorespiratory outcomes applicable to China. The magnitudes of estimates were generally smaller in short-term associations and comparable in long-term associations compared with those in developed countries. Our findings are helpful for future standard revisions and policy formulation. There are still some notable gaps that merit further investigation in China. 相似文献
73.
Congrui Deng Guochen Wang Kan Huang Qingyan Fu Jia Chen Juntao Huo Qianbiao Zhao Yusen Duan Yanfen Lin Fan Yang Wenjie Zhang Hao Li Jian Xu Xiaofei Qin Na Zhao 《环境科学学报(英文版)》2022,34(12):115-127
The coronavirus (COVID-19) pandemic is disrupting the world from many aspects. In this study, the impact of emission variations on PM2.5-bound elemental species and health risks associated to inhalation exposure has been analyzed based on real-time measurements at a remote coastal site in Shanghai during the pandemic. Most trace elemental species decreased significantly and displayed almost no diel peaks during the lockdown. After the lockdown, they rebounded rapidly, of which V and Ni even exceeded the levels before the lockdown, suggesting the recovery of both inland and shipping activities. Five sources were identified based on receptor modeling. Coal combustion accounted for more than 70% of the measured elemental concentrations before and during the lockdown. Shipping emissions, fugitive/mineral dust, and waste incineration all showed elevated contributions after the lockdown. The total non-carcinogenic risk (HQ) for the target elements exceeded the risk threshold for both children and adults with chloride as the predominant species contributing to HQ. Whereas, the total carcinogenic risk (TR) for adults was above the acceptable level and much higher than that for children. Waste incineration was the largest contributor to HQ, while manufacture processing and coal combustion were the main sources of TR. Lockdown control measures were beneficial for lowering the carcinogenic risk while unexpectedly increased the non-carcinogenic risk. From the perspective of health effects, priorities of control measures should be given to waste incineration, manufacture processing, and coal combustion. A balanced way should be reached between both lowering the levels of air pollutants and their health risks. 相似文献
74.
The improvement of safety in the process industries is related to assessment and reduction of risk in a cost-effective manner. This paper addresses the trade-off between risk and cost related to standby safety systems. An age-dependent unavailability model that integrates the effects of the test and maintenance (T&M) activities as well as component ageing is developed and represents the basis for calculating risk. The repair “same-as-new” process is considered regarding the T&M activities. Costs are expressed as a function of the selected risk measure. The time-averaged function of the selected risk measure is obtained from probabilistic safety assessment, i.e. the fault tree analysis. This function is further extended with inclusion of additional parameters related to T&M activities as well as ageing parameters related to component ageing. In that sense, a new model of system unavailability, incorporating component ageing and T&M costs, is presented. The testing strategy is also addressed. Sequential and staggered testings are compared. The developed approach is applied on a standard safety system in nuclear power plant although the method is applicable to standby safety systems that are tested and maintained in other industries as well. The results show that the risk-informed surveillance requirements differ from existing ones in technical specifications, which are deterministically based. Moreover, the presented approach achieves a significant reduction in system unavailability over a relatively small increase of total T&M costs. 相似文献
75.
76.
溶解性有机物(DOM)与区域土地利用的关系:基于三维荧光-平行因子分析(EEM-PARAFAC) 总被引:1,自引:0,他引:1
溶解性有机物(DOM)是水体质量的综合性指标,反映了流域内经济发展和治理保护等多方面因素,可为流域水体保护提供依据.本研究采集了宁波市4个不同城市化程度的区域内的河流样本,运用三维荧光结合平行因子分析法(EEM-PARAFAC)对水体中DOM进行解析,探讨了区域土地利用与DOM的关系.结果表明城市化在含量和组成两方面影响了流域水体中DOM的特征.城市区域(DOC=3.18 mg·L-1)和城乡结合区域(DOC=7.45 mg·L-1)水体中DOM的浓度远高于城市化程度较低的农村区域(DOC为2.16~2.62 mg·L-1,ANOVA,P<0.001).EEM-PARAFAC解析得到7个荧光组分,主要可归为类腐殖质和类蛋白质类物质.其中,城市区域DOM以类腐殖质物质为主,占比达到61.3%;而城乡结合区域由于受到更多的生活污水排放影响,类蛋白质物质的比例最高为59.4%;相比之下,农村区域虽然DOM浓度相对较低,但类腐殖质物质占比达63.6%~65.7%,面源污染是主要原因.主成分分析表明城市化发展对水质具有重要影响,在城市化初期污染主要来源于生活和工业污染源,当城市化到一定水平污染物更多来源于路面径流.本研究表明EEM-PARAFAC可以半定量辨析水体污染源,可为不同的区域水质恢复与治水策略制定提供针对性数据支撑. 相似文献
77.
三种吸附剂对饮用水中铝离子去除率的对比试验 总被引:1,自引:0,他引:1
传统的净水过程一般包括混凝—沉淀—过滤消毒工艺流程,主要去除水中的浊度和细菌,大部分有机物、有害的重金属仍残留在水体中。对活化沸石、聚苯乙烯树脂、活性炭3种材料的净水能力进行了研究。由于3种材料对饮用水中有害物质的去除主要以吸附作用为主,所以在水处理方法中主要阐述了吸附法,包括吸附的机理、吸附的类型、吸附的影响因素。在实验部分,以自来水出水中的铝离子为参照物,利用《生活饮用水卫生标准》国家标准检测方法分别测算出3种材料对铝离子的去除率,借此来比较3种吸附材料的吸附特性。 相似文献
78.
四斗朱水库蓝藻水华爆发成因分析及治理对策研究 总被引:1,自引:0,他引:1
作为饮用水源的小型水库四斗朱连续几年在早春即开始爆发严重束丝藻水华(属于蓝藻)。水质分析发现,四斗朱水库的水质参数如总氮(TN)、总磷(TP)、氨氮(NH4^+-N)以及BOD和COD浓度并不高,但明显高于其上游的石门塘水库,这说明在四斗朱水库的集水区存在污染源。本文分析了在低营养盐浓度情况下四斗朱水库蓝藻水华爆发的原因,认为由于集水区内的农业、生活、水土淋失以及自然沉降等途径导致水库营养浓度升高。并由于未知营养、气温回升以及水库生态系统失衡等因素,导致蓝藻水华暴发。最后,提出了相应的综合治理对策。 相似文献
79.
80.